Investigating Performance Limitations in Cost-Effective Materials for Perovskite Solar Cells (2024.10.24)
Tsukuba, Japan—Perovskite solar cells are attracting attention as next-generation solar technology owing to their highly efficient light-to-electricity conversion. However, 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenylamine)-9,9′-spirobifluorene (spiro-OMeTAD)—a common hole-transport material—has limitations, such as complex synthesis and high cost. To address these challenges, the researchers developed N3,N3,N11,N11-tetrakis(4-methoxyphenyl)[1,4]benzoxazino[2,3,4-kl]phenoxazine-3,11-diamine (HND-2NOMe), a cost-effective, easy to synthesize hole-transport material. HND-2NOMe molecules possess a quasi-planar structure that allows them to align in one-dimensional overlapping manner and thereby facilitates charge transfer. Despite demonstrating high charge mobility, perovskite solar cells incorporating HND-2NOMe have shown performance limitations, such as reduced current, the cause of which is still unknown.
The researchers at University of Tsukuba employed ESR to investigate the underlying mechanisms for the performance limitations of perovskite solar cells incorporating HND-2NOMe, focusing on the material’s internal properties at a microscopic scale. They discovered that in the absence of illumination, holes migrate from perovskite to HND-2NOMe, forming an energetic barrier at the perovskite/HND-2NOMe interface. This barrier impedes hole flow, leading to performance limitations. Furthermore, solar cells incorporating HND-2NOMe demonstrate reduced hole accumulation under solar irradiation, which contributes to the stability of the hole transport function.
Identifying the factors responsible for performance limitations while maintaining stable functionality represents a substantial breakthrough with important implications for formulating fabrication guidelines aimed at enhancing device performance. Furthermore, the aforementioned findings will serve as a valuable foundation for advancing future research and development in perovskite solar cell technologies
For more information, please see the University of Tsukuba press release.
投稿日：2024年10月24日